Dynamical density functional theory: binary phase-separating colloidal fluid in a cavity

Abstract. The dynamical density functional theory of Marconi and Tarazona [J. Chem. Phys., 110, 8032 (1999)], a theory for the non-equilibrium dynamics of the onebody density profile of a colloidal fluid, is applied to a binary fluid mixture of repulsive Gaussian particles confined in a spherical cavity of variable size. For this model fluid there exists an extremely simple Helmholtz free energy functional that provides a remarkably accurate description of the equilibrium fluid properties. We therefore use this functional to test the assumptions implicit in the dynamical density functional theory, rather than any approximations involved in constructing the free energy functional. We find very good agreement between the theory and Brownian dynamics simulations, focusing on cases where the confined fluid exhibits phase separation in the cavity. We also present an instructive derivation of the Smoluchowski equation (from which one is able to derive the dynamical density functional theory) starting from the Liouville equation – a fully microscopic treatment of the colloid and solvent particles. This ‘coarse-graining’ is, of course, not exact and thus the derivation demonstrates the physical assumptions implicit in the Smoluchowski equation and therefore also in the dynamical density functional theory.